Laboratory of Organic Matter Physics

Schematic view of photonic device based on vertical organic nanowires

Organic semiconductor, due to their excellent interaction with light, could be made into photosensors. The scientists of the Laboratory of Organic Physics have been working together with colleagues from University of Strasbourg and CNR Bologna on novel forms of photonic devices. In these, crystalline dioctyl-3,4,9,10-perylenedicarboximide nanowires and 6,13-bis(triisopropylsilylethynyl) pentacene microplates are integrated into a vertical-yet-open asymmetrical heterojunction for the realization of a high-performance organic photovoltaic detector, which shows fast photoresponse, ultrahigh signal-to-noise ratio, and high sensitivity to weak light. The results are published in Advanced Materials.

EQE of semiconducting polymer (P3HT) as a function of illumination position between coplanar metal electrodes.

We have performed a systematic study of dependence of time-resolved photocurrent on the point of charge excitation within the organic semiconductor channel formed by two coplanar metal electrodes. The results confirm that spatial variation of electric field between the electrodes crucially determines transport of photogenerated charge carriers through the organic layer. Time-of-flight measurements of photocurrent demonstrate that the transit time of photogenerated charge carrier packets drifting between the two electrodes decreases with increasing travelling distance. Such counterintuitive result cannot be reconciled with the spatial distribution of electric field between coplanar electrodes, alone. It is also in contrast to expected role of space-charge screening of external electric field. Supported by Monte Carlo simulations of hopping transport in disordered organic semiconductor layer, we submit that the space-charge screens the external electric field and captures slower charge carriers from the photogenerated charge carrier packet. The remaining faster carriers, exhibit velocity distribution with significantly higher mean value and shorter transit time. The work is published in Organic Electronics.

On 25^th of July 2016, the prestigious international journal Nature Nanotechnology has published an article by an international group of scientists from the University of Strasbourg (France) and the University of Nova Gorica (Slovenia). The article presents the results of an experimental study of a novel two dimensional nanostructured photo-sensor. The photo-sensor comprises two-dimensionally aligned semiconducting polymer nanowires, which results to be highly efficient system for the detection of the visible light. This discovery opens the door to the development of fast light photo-sensors, which will be entirely made of organic materials. The sensors exhibit response times below 10 ns and extremely high signal to noise ratios. More can be found here or here (in slovenian language).

Researchers from the University of Nova Gorica (Slovenia), University of Strasbourg & CNRS (France) and the Humboldt University of Berlin (Germany)  have shown that a carefully chosen blend of a small photoswitchable molecule and a semiconducting polymer can be used to fabricate high-performance memory devices that can be written and erased by light. Such multilevel (8-bit!) optical memories have also been implemented on flexible substrates, paving the way to applications in wearable electronics, E-papers, and smart devices. These results have been published in Nature Nanotechnology.

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Our researchers with collaboration of colleagues from MRL laboratory and IJS scientists, found a novel and efficient method used to improve carrier mobilities of poly(3-hexylthiophene) (P3HT)-based organic field effect transistors by means of nanowire formation. The treatment, termed solvation, consists of depositing a small quantity of a solvent directly on top of a previously deposited semiconducting film, and allowing the solvent to evaporate slowly. Such treatment results in an increase of the saturation mobility by more than one order of magnitude, from 1.3 × 10⁻³ up to 3.4 × 10⁻² cm²/Vs, while devices preserve their high ON/OFF ratio of ∼10⁴. The atomic force and scanning electron microscopy studies show that solvated P3HT layers develop a network of nanowires, which exhibit increased degree of structural order, as demonstrated by micro Raman spectroscopy. The time-of-flight photoconductivity studies suggest that higher hole mobility stems from a reduced energy disorder of the transporting states in these structures. More can be found in this paper.

Schematic representation of graphene templating of organic transistor with small molecules or polymer.

Our group published new research in collaboration with colleagues from Max Planck Institute from Mainz. We demonstrated that high-transconductance organic thin film transistors can be achieved by depositing electrochemically exfoliated graphene flakes at the gate-dielectric/organic semiconductor (OS) interface. This effect is applicable to both, solution processed, polymer-based and vacuum-evaporated small-molecule OS-based transistors. Poly(3-hexylthiophene) (P3HT) transistors exhibit a factor of seven higher charge carrier mobility, while pentacene transistors exhibit a fourfold increase in charge carrier mobility, if graphene flakes are present at the dielectric/OS interface. More…

Schematic view of water molecules on the pentacene growth on a single layer graphene

Atomic force microscopy has been used to examine early stages of pentacene growth on exfoliated single-layer graphene transferred to SiO₂ substrates. We have observed 2D growth with mean height of 1.5 ± 0.2 nm on as-transferred graphene. Three-dimensional islands of pentacene with an average height of 11 ± 2 nm were observed on graphene that was annealed at 350 °C prior to pentacene growth. Compellingly similar 3D morphology has been observed on graphene transferred onto SiO₂ that was treated with hexamethyldisilazane prior to the transfer of graphene. On multilayer graphene we have observed 2D growth, regardless of the treatment of SiO₂. We interpret this behavior of pentacene molecules in terms of the influence of the dipolar field that emerges from the water monolayer at the graphene/SiO₂ interface on the surface energy of graphene. This work was published in Langmuir.

Schematic view of photocurrent dynamics in composite layers.

In collaboration with the University of Strasbourg and ISOF-CNR Bologna, Italy, our group published results of a study of graphene/organic semiconductor composites. Organic thin-film transistor transfer characteristics and time-of-flight (TOF) photoconductivity measurements were used to investigate the effect of the addition of liquid-phase exfoliated graphene nanoflakes (GNs) on the electron mobility in thin films of N,N’-1H,1H-perfluorobutyl dicyanoperylene-carboxydi-imide (PDIF-CN2). Transfer characteristics measurements reveal that the charge carrier mobility of PDIF-CN2 increases by almost three orders of magnitude via blending with GNs. TOF photocurrent measurements confirm that the GNs improve the charge carrier transport in PDIF-CN2. We have found a strong dependence of the TOF-determined electron mobility on the excitation wavelength and obtained a maximum mobility of 0.17 cm2/Vs for charge carriers produced in GN: PDIF-CN2 blends, using photon energy of 5.9 eV. This value is in good agreement with the field-effect mobility of 0.2 cm2/Vs determined from data recorded in the low-voltage region of transfer characteristics. More information can be found in the article.

The difference of pentacene morphology on single and bilayer graphene

Using atomic force microscopy we have examined morphology of sub-monolayer thick pentacene layers, deposited on exfoliated single-layer and bilayer graphene, transferred onto SiO₂. We observe two-dimensional island growth in the range of substrate temperatures from 10 to 60 °C. We find that island size distributions on single-layer graphene are broader and centered at higher average island areas than on bilayer graphene. We have found activation energy for molecule aggregation of E_a = 427 ± 25 and E_a = 537 ± 46 meV for single layer and bilayer graphene, respectively. We associate the observed differences in pentacene layer morphology with the influence of the dipole field that can be associated with the water layer at the graphene/SiO₂ interface. More can be found in this paper

Time-of-flight photoconductivity measurements of four different phases of TES-ADT material.

Together with Imperial College, Holst Centre, ICMM Madrid, University of Kentucky and ETH Zürich  we have been investigating electric transport properties of  5,11-bis(triethylsilylethynyl) anthradithiophene (TES ADT). TES ADT– one of the most promising, solution-processable small-molecular organic semiconductors – was analyzed, revealing the highest performing polymorph among four solid-state phases, opening pathways toward the reliable fabrication of high-performance bottom-gate/bottom-contact transistors. The results are published in Chemistry of Materials.